Why Some Salts are Neutral, Acidic, or Basic

in salt •  last month

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    Salts are essentially the product of any base reacting with any acid.
    Some salts are neutral - these are the products of STRONG bases with STRONG acids (e.g.: NaCl).
    Some salts are acidic - these are the products of WEAK bases with STRONG acids (e.g.: NH4Cl).
    And some salts are alkaline/basic - these are the products of STRONG bases with WEAK acids (e.g.: Na2CO3)
    The reason for whether or not salts are acidic/neutral/alkaline has to do with chemical equilibriums, which is a subset of physical chemistry. I think at your current level, it is not important to get into
    I will merely give you some examples for how it works.
    To make NaCl
    we'll make NaOH + HCl -> NaCl + H2O
    that NaCl will dissolve and dissociate (split) to NaCl -> Na+ + Cl-
    Neither Na+ or Cl- withh hydrolise - that is, react with water.
    To make NH4Cl, we'll mix NH3 + HCl -> NH4Cl
    NH4Cl dissolves and dissociates (splits up) in an equilibrium (indicated by arrows pointing both ways) to NH4Cl <-> NH4+ + Cl-
    Cl- does NOT hydrolise
    NH4+ however, DOES hydrolise. It hydrolises thusly in an equilibrium: NH4+ + H2O <-> NH3 + H3O+
    Because more H3O+ is produced at the end of this reaction chain, the solution becomes ACIDIC.

    To make Na2CO3 we'll mix 2NaOH + H2CO3 -> Na2CO3 + 2H2O
    Na2CO3 dissolves and dissociates in an equilibrium to Na2CO3 -> 2Na+ + CO3(2)-
    Na+ does NOT hydrolise
    CO3(2)- hydrolises to CO3(2)- + H2O <-> HCO3- + OH- and HCO3- + H2O <-> H2CO3 + OH-
    The reaction is done in 2 steps, with the second one occuring in much smaller ratio to the first one. However, both produce OH-, meaning the solution becomes alkaline.
    THe important take away is that ions left over from a STRONG acid/base (e.g.: Na+, Cl-) do NOT hydrolise. terracore
    The ions left over from a WEAK (acid/base) (e.g.: NH4+, CO3(2)-) DO hydrolise.
    Weak acids/bases are very roughly defined by needing to dissolve more moles of them than strong acids/bases to reach the same pH. This is because when dissolved, they do not dissociate entirely (meaning, they enter an equilibrium).

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